Aromatic Hydrocarbons: Introduction, IUPAC nomenclature, benzene: resonance, aromaticity, chemical properties: mechanism of electrophilic substitution. Nitration, sulphonation, halogenation, Friedel Craft's alkylation and acylation, directive influence of functional group in monosubstituted benzene. Carcinogenicity and toxicity.
CLASS -XII Unit Portion to be Reduced
1 . Solid State:- Electrical and magnetic properties. Band theory of metals, conductors, semiconductors and insulators and n and p type semi conductors.
2. Solutions :- Abnormal molecular mass, Van't Hoff factor
3. Electrochemistry Lead accumulator, fuel cells, corrosion, law of electrolysis (elementary idea), dry cell- electrolytic cells and Galvanic cells,
4 . Chemical Kinetics Concept of collision theory (elementary idea, no mathematical treatment), activation energy, Arrhenius equation.
5 . Surface Chemistry emulsion - types of emulsions, catalysis: homogenous and heterogeneous, activity and selectivity of solid catalysts; enzyme catalysis,
6 . General Principles and Processes of Isolation of Elements -Entire unit
7 . p-Block Elements :- Preparation and properties of Phosphine, Sulphuric Acid: industrial process of manufacture, Oxides of Nitrogen (Structure only); Phosphorus - allotropic forms, compounds of Phosphorus: Preparation and properties of Halides and Oxo acids (elementary idea only).
8. d and f Block Elements :-Chemical reactivity of lanthanoids, Actinoids -Electronic configuration, oxidation states and comparison with lanthanoids. Preparation and properties of KMnO4 and K2Cr2O7
9. Coordination Compounds Structure and stereoisomerism, importance of coordination compounds (in qualitative analysis, extraction of metals and biological system).
10. Haloalkanes and Haloarenes :-Uses and environmental effects of -dichloromethane, tri chloromethane, tetrachloromethane, iodoform, freons, DDT.
11 . Alcohols, Phenols and Ethers :-uses with special reference to methanol and ethanol.
12 . Aldehydes, Ketones and Carboxylic Acid --- NOTHINGS
13. Amines Diazonium salts: -Preparation, chemical reactions and importance in synthetic organic chemistry.
14. Biomolecules:- Oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen), importance of carbohydrates. Vitamins– classification and functions. Enzymes. Hormones - Elementary idea excluding structure.
15 . Polymers entire chapter
16. Chemistry in Everyday life entire chapter
REVISED SYLLABUS FOR CLASS XII (2020-21) (THEORY)
Unit I: Solid State 8 Periods
Classification of solids based on different binding forces: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea). Unit cell in two dimensional and three dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids, number of atoms per unit cell in a cubic unit cell, point defects.
Unit II: Solutions 8 Periods
Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in liquids, solid solutions, Raoult's law, colligative properties - relative lowering of vapour pressure, elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties.
Unit III: Electrochemistry 7 Periods
Redox reactions, EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells, Relation between Gibbs energy change and EMF of a cell, conductance in electrolytic solutions, specific and molar conductivity, variations of conductivity with concentration, Kohlrausch's Law, electrolysis.
Unit IV: Chemical Kinetics 5 Periods
Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration, temperature, catalyst; order and molecularity of a reaction, rate law and specific rate constant, integrated rate equations and half-life (only for zero and first order reactions).
Unit V: Surface Chemistry 5 Periods
Adsorption - physisorption and chemisorption, factors affecting adsorption of gases on solids, colloidal state: distinction between true solutions, colloids and suspension; lyophilic, lyophobic, multi-molecular and macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement, electrophoresis, coagulation.
Unit VII:p-Block Elements 7 Periods
Group -15 Elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties; Nitrogen preparation properties and uses; compounds of Nitrogen: preparation and properties of Ammonia and Nitric Acid.
Group 16 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties, dioxygen: preparation, properties and uses, classification of Oxides, Ozone, Sulphur -allotropic forms; compounds of Sulphur: preparation properties and uses of Sulphur-dioxide, Sulphuric Acid: properties and uses; Oxoacids of Sulphur (Structures only).
Group 17 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens, Preparation, properties and uses of Chlorine and Hydrochloric acid, interhalogen compounds, Oxoacids of halogens (structures only).
Group 18 Elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.
Unit VIII: d and f Block Elements 7 Periods
General introduction, electronic configuration, occurrence and characteristics of transition metals, general trends in properties of the first row transition metals – metallic character, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds, alloy formation. Lanthanoids - Electronic configuration, oxidation states and lanthanoid contraction and its consequences.
Unit IX: Coordination Compounds 8 Periods Coordination compounds - Introduction, ligands, coordination number, colour, magnetic properties and shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner's theory, VBT, and CFT.
Unit X: Haloalkanes and Haloarenes. 9 Periods Haloalkanes: Nomenclature, nature of C–X bond, physical and chemical properties, optical rotation mechanism of substitution reactions. Haloarenes: Nature of C–X bond, substitution reactions (Directive influence of halogen in monosubstituted compounds only).
Unit XI: Alcohols, Phenols and Ethers 9 Periods Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary alcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydration. Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophillic substitution reactions, uses of phenols. Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.
Unit XII: Aldehydes, Ketones and Carboxylic Acids 10 Periods Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical and chemical properties, mechanism of nucleophilic addition, reactivity of alpha hydrogen in aldehydes, uses. Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses.
Unit XIII: Amines 7 Periods Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary, secondary and tertiary amines.
Unit XIV: Biomolecules 8 Periods Carbohydrates - Classification (aldoses and ketoses), monosaccahrides (glucose and fructose), D-L configuration Proteins -Elementary idea of - amino acids, peptide bond, polypeptides, proteins, structure of proteins - primary, secondary, tertiary structure and quaternary structures (qualitative idea only), denaturation of proteins. Nucleic Acids: DNA and RNA.